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Solvent-induced lone pair activity tuning and vapoluminescence in a Pt2Pb cluster
Jesús R. Berenguer, Elena Lalinde, Antonio Martín, M. Teresa Moreno, Santiago Ruiz, Sergio Sánchez and Hamid R. Shahsavaria
Chem. Commun. 2013, 49, 5067-5069
DOI: 10.1039/C3CC41638K

We report a novel cluster, [{Pt(C6F5)(bzq)}2Pb(Spy)2] 1, that displays reversible vapoluminescence to specific organic vapours; this behaviour can be related to the stereochemical activity of the lone pair around the PbII in the ground state and to the distinct distortion of the coordination environment (1 and 1-solvent) upon photoexcitation.

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