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Fluorocarbons Modulate the Coordination Sphere of f-Element Complexes
Santiago Álvarez, Babil Menjón
Angew. Chem. Int. Ed. 2014, 53, 2810-2811
DOI: 10.1002/anie.201310916

Weak yet influential: Fluorocarbons, the least coordinating of all halocarbons, establish secondary coordinative interactions with f elements. These interactions affect the stereochemistry of the complexes and provide examples of coordination polyhedra along distortion paths not seen before.

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