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Platinum-mediated monohydration of SO2
Antonio Gimeno-Prat, Adrián Cortés, Antonio Martín, Miguel Baya and José M. Casas
Dalton Trans. 2018, 47, 16848-16849
DOI: 10.1039/C8DT04169E

The monohydration of SO2 has been achieved in solution mediated by a platinum-aquo complex. Benzamidate ligands play a key role along the process, acting as versatile proton shuttles. Finally, the platinum center allows the stabilization of benzimidic acid and a hydrogensulphite anion, the disfavored tautomers of benzamide and sulphonate, respectively.

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