Different Patterns of Pd-Promoted C-H Bond Activation in (Z)-4-Hetarylidene-5(4H)-oxazolones and Consequences in Photophysical Properties
Miguel Martínez, David Dalmau, Olga Crespo, Pilar García-Orduña, Fernando Lahoz, Antonio Martín and Esteban P. Urriolabeitia
Inorganics 2024, 12, 271
DOI: 10.3390/inorganics12100271


Gold trifluoromethyl complexes as efficient regioselective catalysts in alkyne hydration
David Ruiz-Almoguera, David Ventura-Espinosa, Alberto Pérez-Bitrián, Antonio Martín, José A Mata, Miguel Baya
Chem. Eur. J. 2024, e202401753
DOI: 10.1002/chem.202401753


Protective Effect of the Perchlorophenyl Group in Organophosphorus Chemistry
Mª Ángeles García-Monforte, Miguel Baya, Antonio Martín, Babil Menjón
J. Organomet. Chem. 2024, 1022, 123385
DOI: 10.1016/j.jorganchem.2024.123385


Gold trifluoromethyl complexes as efficient regioselective catalysts in alkyne hydration
David Ruiz-Almoguera, David Ventura-Espinosa, Alberto Pérez-Bitrián, Antonio Martín, José A Mata, Miguel Baya
Chem. Eur. J. 2024, e202401753
DOI: 10.1002/chem.202401753


The CF3 Group as a Synthon of the CF+ Unit in Palladium Chemistry
Daniel Joven-Sancho, Miguel Baya, Antonio Martín, Jesús Orduna, Babil Menjón
Angew. Chem. 2024, e202403108
DOI: 10.1002/anie.202403108


Synthesis and Lewis Acid Properties of Neutral Silver(III) Adducts Containing the AgIII(CF3)3 Moiety
Luca Demonti, Daniel Joven-Sancho, Nathalie Saffon-Merceron, Miguel Baya, Noel Nebra
Chem. Eur. J. 2024, e202400881
DOI: 10.1002/chem.202400881


Pyrazolate-Bridged NHC Cyclometalated [Pt2] Complexes and [Pt2Ag(PPh3)]+ Clusters in Electroluminescent Devices
Jorge Roy, Michele Forzatti, Lorenzo Arnal, Antonio Martín, Sara Fuertes, Daniel Tordera and Violeta Sicilia
Inorg. Chem. 2024, 63, 7275–7285
DOI: 10.1021/acs.inorgchem.4c00105


NIR-II Emission from Cyclometalated Dinuclear Pt(III) Complexes
Irene Melendo, Sara Fuertes, Antonio Martín, Violeta Sicilia
Inorg. Chem. 2024, 63, 5470–5480
DOI: 10.1021/acs.inorgchem.3c04314


The Fluoride Method: Access to Silver(III) NHC Complexes
Juan Pueyo, Daniel Joven-Sancho, Antonio Martín, Babil Menjón, Miguel Baya
Chem. Eur. J. 2024, e202303937
DOI: 10.1002/chem.202303937


A cyclometalated N-heterocyclic carbene and acetylacetonate ligands in a phosphorescent Pt(II) dye for sensing glucose
Irene Melendo, Javier Camacho-Aguayo, Sareh Paziresh, Sara Fuertes, Antonio Martín, Susana de Marcos, Javier Galbán, Violeta Sicilia
Dyes and Pigments 2023, 219, 111630
DOI: 10.1016/j.dyepig.2023.111630


Electrophilicity of neutral square-planar organosilver(III) compounds
Daniel Joven-Sancho, Luca Demonti, Antonio Martín, Nathalie Saffon-Merceron, Noel Nebra, Miguel Baya and Babil Menjón
Chem. Commun. 2023, 59, 4166-4168
DOI: 10.1039/D3CC00493G


Terminal Au-N and Au-O Units in Organometallic Frames
Alberto Pérez-Bitrián, Santiago Álvarez, Miguel Baya, Jorge Echeverría, Antonio Martín, Jesús Orduna, Babil Menjón
Chem. Eur. J. 2023, 29, e202203181
DOI: 10.1002/chem.202203181


Green light-emitting electrochemical cells based on platinum(II) complexes with a carbazole-appended carbene ligand
Sara Fuertes, Lorenzo Mardegan, Ignacio Martínez, Silvia Ventura, Irene Ara, Daniel Tordera, Henk J. Bolink and Violeta Sicilia
J. Mater. Chem. C 2022, 61, 12559–12569
DOI: 10.1039/D2TC02539F


High-Valent Pyrazolate-Bridged Platinum Complexes: A Joint Experimental and Theoretical Study
Lorenzo Arnal, Daniel Escudero, Sara Fuertes, Antonio Martín, and Violeta Sicilia
Inorg. Chem. 2022, 61, 12559–12569
DOI: 10.1021/acs.inorgchem.2c01441


Trans-Amidate Platinum Complexes Anchoring Water and N-donor Molecules. The Importance of Hydrogen Bonding
Antonio Gimeno-Prat, Antonio Martín, Miguel Baya, José M. Casas
Eur. J. Inorg. Chem. 2022, e202200163
DOI: 10.1002/ejic.202200163


Heteropolymetallic Architectures as Snapshots of Transmetallation Processes at Different Degrees of Transfer
David Campillo, Daniel Escudero, Miguel Baya, Antonio Martín
Chem. Eur. J. 2022, 28, e202104538
DOI: 10.1002/chem.202104538


The First Five-coordinate Compound with Inverted Ligand Field: An Unprecedented Geometry for Silver(III)
Babil Menjón, Daniel Joven-Sancho, Miguel Baya, Antonio Martín, Jesús Orduna
Angew. Chem. 2021, 60, 26545-26549
DOI: 10.1002/anie.202112449


Chameleonic Photo- and Mechanoluminescence in Pyrazolate-Bridged NHC Cyclometalated Platinum Complexes
Violeta Sicilia, Lorenzo Arnal, Daniel Escudero, Sara Fuertes, and Antonio Martín
Inorg. Chem. 2021, 60, 12274–12284
DOI: 10.1021/acs.inorgchem.1c01470


Stability of AgIII towards Halides in Organosilver(III) Complexes
Babil Menjón, Daniel Joven-Sancho, Miguel Baya, Larry Rocco Falvello, Antonio Martín, Jesús Orduna
Chem. Eur. J. 2021, 27, 12796-12806
DOI: 10.1002/chem.202101859


A Multifunctional Dysprosium-Carboxylato 2D Metall–Organic Framework
Jonay González, Pablo Sevilla, Guillem Gabarró-Riera, Jesús Jover, Jorge Echeverría, Sara Fuertes, Ana Arauzo, Elena Bartolomé, E. Carolina Sañudo
Angew. Chem. 2021, 60, 12001-12006
DOI: 10.1002/anie.202100507


Structural Insights into the Vapochromic Behavior of Pt- and Pd-Based Compounds
Benny Danilo Belviso, Francesco Marin, Sara Fuertes, Violeta Sicilia, Rosanna Rizzi, Fulvio Ciriaco, Chiara Cappuccino, Eric Dooryhee, Aurelia Falcicchio, Lucia Maini, Angela Altomare, and Rocco Caliandro
Inorg. Chem. 2021, 60, 6349-6366
DOI: 10.1021/acs.inorgchem.1c00081


Hydrogen bonding to metals as a probe for inverted ligand field
Alberto Pérez-Bitrián, Miguel Baya, José M. Casas, Antonio Martín and Babil Menjón
Dalton Trans. 2021, 50, 5465–5472
DOI: 10.1039/D1DT00597A


Platinum and palladium promoted couplings of bridging PPh2- with terminally bonded ligands
Piero Mastrorilli and Consuelo Fortuño
Inorg. Chim. Acta 2020, 513, 119947
DOI: 10.1016/j.ica.2020.119947


Cyclometalated NHCs Pt(II) Compounds with Chelating P^P and S^S Ligands: From Blue to White Luminescence
Sara Jaime, Lorenzo Arnal, Violeta Sicilia, and Sara Fuertes
Organometallics 2020, 39, 3695-3704
DOI: 10.1021/acs.organomet.0c00510


Coumarin-lanthanide based compounds with SMM behavior and high quantum yield luminescence
A. Arauzo, L. Gasque, S. Fuertes, C. Tenorio, S. Bernés and E. Bartolomé
Dalton Trans. 2020, 49, 13671-13684
DOI: 10.1039/D0DT02614J


Metal-Metal Cooperation in the Oxidation of a Flapping Platinum Butterfly by Haloforms: Experimental and Theoretical Evidence
Violeta Sicilia, Lorenzo Arnal, Sara Fuertes, Antonio Martín, and Miguel Baya
Inorg. Chem. 2020, 59, 12586–12594
DOI: 10.1021/acs.inorgchem.0c01701


Stable mixed-valence diphenylphosphanido bridged platinum(ii)-platinum(iv) complexes
Consuelo Fortuño, Antonio Martín, Piero Mastrorilli, Mario Latronico, Valentina Petrelli and Stefano Todisco
Dalton Trans. 2020, 49, 4935-4955
DOI: 10.1039/D0DT00712A


The First Organosilver(III) Fluoride, [PPh4][(CF3)3AgF]
Daniel Joven‐Sancho, Miguel Baya, Antonio Martín, Jesús Orduna, Babil Menjón
Chem. Eur. J. 2020, 26, 4471-4475
DOI: 10.1002/chem.201905771


Highly Photoluminescent Blue Ionic Platinum-Based Emitters
Violeta Sicilia, Lorenzo Arnal, Andrés J. Chueca, Sara Fuertes, Azin Babaei, Ana María Igual Muñoz, Michele Sessolo and Henk J. Bolink
Inorg. Chem. 2020, 59, 1145-1152
DOI: 10.1021/acs.inorgchem.9b02782


The Influence of Cyclometalated Ligand Motifs on the Solid-State Assemblies and Luminescent Properties of Pt(II)-Tl(I) Complexes
Sareh Paziresh, Violeta Sicilia, Irene Ara, Antonio Martín, Sara Fuertes
Organometallics 2019, 38, 3804-3815
DOI: 10.1021/acs.organomet.9b00500


Synthesis and characterization of binuclear Pt(IV) complexes and tetranuclear mixed valence complexes of Platinum(II)-Platinum(IV)
José M. Casas, Beatriz E. Diosdado, Juan Forniés, Ma Ángeles García-Monforte, Raquel Laporta, Antonio Martín, Milagros Tomás
J. Oganomet. Chem. 2019, 897, 130-138
DOI: 10.1016/j.jorganchem.2019.06.034


Increasing Lewis acidity in perchlorophenyl derivatives of antimony
Ma Ángeles García-Monforte, Miguel Baya, Daniel Joven-Sancho, Irene Ara, Antonio Martín, Babil Menjón
J. Oganomet. Chem. 2019, 897, 185-191
DOI: 10.1016/j.jorganchem.2019.06.033


M-C Bond Homolysis in Coinage-Metal [M(CF3)4]- Derivatives
Babil Menjón, Miguel Baya, Daniel Joven-Sancho, Pablo J. Alonso, Jesús Orduna
Angew. Chem. Int. Ed. 2019, 58, 9954-9958
DOI: 10.1002/anie.201903496


Mixed Valence Pt(II),Pt(IV),Pt(II) Complexes from a Diplatinum(III) Synthon and Sulfur-Based Anions
Consuelo Fortuño, Antonio Martín, Piero Mastrorilli, Stefano Todisco, and Mario Latronico
Organometallics 2019, 38, 2042-2052
DOI: 10.1021/acs.organomet.9b00096


New NHC cycloplatinated compounds. Significance of the cyclometalated group on the electronic and emitting properties of bis-cyanide compounds
Sara Fuertes, Andrés J. Chueca, Antonio Martín, Violeta Sicilia
J. Organomet. Chem. 2019, 889, 53-61
DOI: 10.1016/j.jorganchem.2019.03.012


Double rollover cycloplatinated(II) skeleton: a versatile platform for tuning emission by chelating and non-chelating ancillary ligand systems
Sareh Paziresh, Reza Babadi Aghakhanpour, Sara Fuertes, Violeta Sicilia, Fatemeh Niroomand Hosseini and S.Masoud Nabavizadeh
Dalton Trans. 2019, 48, 5713-5724
DOI: 10.1039/C9DT00807A


Highly Efficient Platinum-Based Emitters for Warm White Light Emitting Diodes
Violeta Sicilia, Sara Fuertes, Andrés J. Chueca, Lorenzo Arnal, Antonio Martín, Mariano Perálvarez, Chiara Botta and Umberto Giovanella
J. Mat. Chem. C 2019, 7, 4509-4516
DOI: 10.1039/C9TC00747D


New Pt→M (M = Ag, Tl) complexes based on anionic cyclometalated Pt(II) complexes
David Campillo, Úrsula Belío and Antonio Martín
Dalton Trans. 2019, 48, 3270-3283
DOI: 10.1039/C8DT04169E


Platinum-mediated monohydration of SO2
Antonio Gimeno-Prat, Adrián Cortés, Antonio Martín, Miguel Baya and José M. Casas
Dalton Trans. 2018, 47, 16846-16849
DOI: 10.1039/C8DT04169E


A Cyclometalated N-Heterocyclic Carbene: The Wings of The First Pt2(II,II) Butterfly oxidized by CHI3
Violeta Sicilia, Lorenzo Arnal, Sara Fuertes, Antonio Martín, Miguel Baya
Chem. Eur. J. 2018, 24, 18743-18748
DOI: 10.1002/chem.201804013


Iridium complexes catalysed the selective dehydrogenation of glucose to gluconic acid in water
Pilar Borja, Cristian Vincent, Miguel Baya, Hermenegildo García and José A. Mata
Green. Chem. 2018, 20, 4094-4101
DOI: 10.1039/C8GC01933A


Homoleptic Trifluoromethyl Derivatives of Ag(I) and Ag(III)
Babil Menjón, Daniel Joven-Sancho, Miguel Baya, Antonio Martín
Chem. Eur. J. 2018, 24, 13098-13101
DOI: 10.1002/chem.201802960


Pt-M complexes (M = Ag, Au) as models for intermediates in transmetalation processes
Antonio Martín, Miguel Baya, Úrsula Belío, David Campillo, Israel Fernández, Sara Fuertes.
Chem. Eur. J. 2018, 24, 13879-13889
DOI: 10.1002/chem.201802542


The Use of Cyclometalated NHCs and Pyrazoles for the Developement of Fully Efficient Blue Pt(II) Emitters and Pt/Ag Clusters
Violeta Sicilia, Lorenzo Arnal, Sara Fuertes, Antonio Martín.
Chem. Eur. J. 2018, 24, 9377-9384
DOI: 10.1002/chem.201800646


Heteronuclear {TbxEu1-x} furoate 1D polymers presenting luminescent properties and SMM behavior
E. Bartolomé, J. Bartolomé, A. Arauzo, J. Luzón, R. Cases, S. Fuertes, V. Sicilia, A. I. Sánchez-Cano, J. Aporta, S. Melnic, D. Prodius and S. Shova.
J. Mater. Chem. C 2018, 6, 5286-5299
DOI: 10.1039/C8TC00832A


An Organogold(III) Difluoride with trans Arrangement
Babil Menjón, Alberto Pérez-Bitrián, Miguel Baya, José María Casas, Antonio Martín, Jesús Orduna.
Angew. Chem. Int. Ed. 2018, 57, 6517-6521
DOI: 10.1002/anie.201802379


High Production of Hydrogen on Demand from Silanes Catalyzed by Iridium Complexes as a Versatile Hydrogen Storage System
David Ventura-Espinosa, Sara Sabater, Alba Carretero-Cerdán, Miguel Baya, and Jose A. Mata.
ACS Catal. 2018, 8, 2558-2566
DOI: 10.1021/acscatal.7b04479


Gold(II) Trihalide Complexes from Organogold(III) Precursors
Miguel Baya, Alberto Pérez-Bitrián, Sonia Martínez-Salvador, Antonio Martín, José M. Casas, Babil Menjón and Jesús Orduna.
Chem. Eur. J. 2018, 24, 1514-1517
DOI: 10.1002/chem.201705509


A route to small clusters: a twisted half-hexagram-shaped M4(OH)4 cluster and its capacity for hosting closed-shell metals
Irene Ara, María Ángeles García Monforte, R. González, Larry R. Falvello, Milagros Tomás
Chem. Commun. 2017, 53, 13121-13124
DOI: 10.1039/C7CC07712B


Solvent-Driven P-S vs P-C Bond Formation from a Diplatinum(III) Complex and Sulfur-Based Anions
Consuelo Fortuño, Antonio Martín, Piero Mastrorilli, Vito Gallo and Stefano Todisco
Organometallics 2017, 36, 4325-4337
DOI: 10.1021/acs.organomet.7b00746


(CF3)3Au as a Highly Acidic Organogold(III) Fragment
Alberto Pérez-Bitrián, Miguel Baya, José M. Casas, Larry R. Falvello, Antonio Martín, Babil Menjón
Chem. Eur. J. 2017, 23, 14918-14930
DOI: 10.1002/chem.201703352


Catalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On-demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrier
David Ventura-Espinosa, Alba Carretero-Cerdán, Miguel Baya, Hermenegildo García, José A. Mata
Chem. Eur. J. 2017, 23, 10815-10821
DOI: 10.1002/chem.201700243


Pt2Tl Building Blocks for Two-Dimensional Extended Solids: Synthesis, Crystal Structures, and Luminescence
Sara Fuertes, Andrés J. Chueca, Antonio Martín, and Violeta Sicilia
Cryst. Growth Des. 2017, 17, 4336-4346
DOI: 10.1021/acs.cgd.7b00662


Heteroleptic Cycloplatinated N-Heterocyclic Carbene Complexes: A New Approach to Highly Efficient Blue-Light Emitters
Sara Fuertes, Andrés J. Chueca, Lorenzo Arnal, Antonio Martín, Umberto Giovanella, Chiara Botta, and Violeta Sicilia
Inorg. Chem. 2017, 59, 4829-4839
DOI: 10.1021/acs.inorgchem.6b02826


Anionic Derivatives of Perfluorinated Trimethylgold
Babil Menjón, Alberto Pérez-Bitrián, Sonia Martínez-Salvador, Miguel Baya, José M. Casas, Antonio Martín and Jesús Orduna
Chem. Eur. J. 2017, 23, 6919-6929
DOI: 10.1002/chem.201700927


Gold(I) Fluorohalides: Theory and Experiment
Miguel Baya, Alberto Pérez-Bitrián, Sonia Martínez-Salvador, José M. Casas, Babil Menjón and Jesús Orduna
Chem. Eur. J. 2017, 23, 1512-1515
DOI: 10.1002/chem.201605655


Binuclear Complexes and Extended Chains Featuring Pt(II)-Tl(I) Bonds: Influence of the Pyridine-2-Thiolate and Cyclometalated Ligands on the Self-Assembly and Luminescent Behavior
Jesús R. Berenguer, Elena Lalinde, Antonio Martín, M. Teresa Moreno, Sergio Sánchez, and Hamid R. Shahsavari
Inorg. Chem. 2016, 55, 7866-7878
DOI: 10.1021/acs.inorgchem.6b00699


Ruthenium molecular complexes immobilized on graphene as active catalysts for the synthesis of carboxylic acids from alcohol dehydrogenation
David Ventura-Espinosa, Cristian Vicent, Miguel Baya and José A. Mata
Catal. Sci. Technol. 2016, 6, 8024-8035
DOI: 10.1039/C6CY01455K


White Light Emission from Planar Remote Phosphor Based on NHC Cycloplatinated Complexes
Sara Fuertes, Andrés J. Chueca, Mariano Perálvarez, Pilar Borja, Marc Torrell, Josep Carreras, and Violeta Sicilia
Appl. Mater. Interfaces 2016, 8, 16160-16169
DOI: 10.1021/acsami.6b03288


Synthesis and reactivity of phosphanido bridged 1,1′-bis(diphenylphosphino)ferrocene complexes [(RF)2Pt(μ-PPh2)2M(dppf)] [M = Pt, Pd]
Daniela Giardina-Papa, Irene Ara, Susana Ibáñez, Piero Mastrorilli, Vito Gallo, Juan Forniés
Polyhedron 2016, 120, 44-53
DOI: 10.1016/j.poly.2016.05.040


Unusual Metal-Metal Bonding in a Dinuclear Pt-Au Complex: Snapshot of a Transmetalation Process
Miguel Baya, Úrsula Belío, Israel Fernández, Sara Fuertes, and Antonio Martín
Angew. Chem. Int. Ed. 2016, 55, 6978-6982
DOI: 10.1002/anie.201602081


Polynuclear platinum phosphanido/phosphinito complexes: formation of P-O and P-O-P bonds through reductive coupling processes
Irene Ara, Juan Forniés, Susana Ibáñez, Piero Mastrorilli, Stefano Todisco and Vito Gallo
Dalton Trans. 2016, 45, 2156-2171
DOI: 10.1039/C5DT02593A


Exploring the Transphobia Effect on Heteroleptic NHC Cycloplatinated Complexes
Sara Fuertes, Andrés J. Chueca, and Violeta Sicilia
Inorg. Chem. 2015, 54, 9885-9895
DOI: 10.1021/acs.inorgchem.5b01655


A hexanuclear gold carbonyl cluster
Sonia Martínez-Salvador, Larry R. Falvello, Antonio Martín and Babil Menjón
Chem. Sci. 2015, 6, 5506-5510
DOI: 10.1039/C5SC01578B


Oxidation of Half-Lantern Pt2(II,II) Compounds by Halocarbons. Evidence of Dioxygen Insertion into a Pt(III)-CH3 Bond
V. Sicilia, M. Baya, P. Borja, and A. Martín
Inorg. Chem. 2015, 54, 7316-5510
DOI: 10.1021/acs.inorgchem.5b00846


Multinuclear Solid-State NMR and DFT Studies on Phosphanido-Bridged Diplatinum Complexes
Piero Mastrorilli, Stefano Todisco, Alessandro Bagno, Vito Gallo, Mario Latronico, Consuelo Fortuño, and Dietrich Gudat
Inorg. Chem. 2015, 54, 5855-5863
DOI: 10.1021/acs.inorgchem.5b00627


An extended Chain and Trinuclear Complexes Based on Pt(II)-M (M = Tl(I), Pb(II)) Bonds: Contrasting Photophysical Behaviour
Juan Forniés, Nora Giménez, Susana Ibáñez, Elena Lalinde, Antonio Martín, and M. Teresa Moreno
Inorg. Chem 2015, 54, 4351-4363
DOI: 10.1021/acs.inorgchem.5b00083


Selective turn-off phosphorescent and colorimetric detection of mercury(II) in water by half-lantern platinum(II) complexes
Violeta Sicilia, Pilar Borja, Miguel Baya and José M. Casas
Dalton 2015, 44, 6936-6943
DOI: 10.1039/C5DT00087D


Stepwise Strategy to Cyclometallated PtII Complexes with N-Heterocyclic Carbene Ligands: A Luminescence Study on New β-Diketonate Complexes
Sara Fuertes, Hector García, Mariano Perálvarez, Wim Hertog, Josep Carreras and Violeta Sicilia
Chem. Eur. J. 2015, 21, 1620-1631
DOI: 10.1002/chem.201404915


Neutral benzoquinolate cyclometalated platinum(II) complexes as precursors in the preparation of luminescent Pt-Ag complexes
Miguel Baya, Úrsula Belío, Juan Forniés, Antonio Martín, Mariano Perálvarez, Violeta Sicilia
Inorg. Chim. Acta 2015, 424, 136-149
DOI: 10.1016/j.ica.2014.07.059


Highly Active Cp*Ir Catalyst at Low Temperatures Bearing an N-Heterocyclic Carbene Ligand and a Chelated Primary Benzylamine in Transfer Hydrogenation
Sara Sabater, Miguel Baya, and Jose A. Mata
Organometallics 2014, 33, 6830-6839
DOI: 10.1021/om500888d


Stereochemistry of Complexes with Double and Triple Metal-Ligand Bonds: A Continuous Shape Measures Analysis
Santiago Álvarez, Babil Menjón, Andrés Falceto, David Casanova, and Pere Alemany
Inorg. Chem. 2014, 53, 12151-12163
DOI: 10.1021/ic5021077


Homoleptic Organocobalt(III) Compounds with Intermediate Spin
M. Angeles García-Monforte, Irene Ara, Antonio Martín, Babil Menjón, Milagros Tomás, Pablo J. Alonso, Ana B. Arauzo, Jesús I. Martínez, and Conrado Rillo
Inorg. Chem. 2014, 53, 12384-12395
DOI: 10.1021/ic501719y


Half-Lantern Pt(II) and Pt(III) Complexes. New Cyclometalated Platinum Derivatives
Violeta Sicilia, Pilar Borja, Antonio Martín
Inorganics 2014, 2, 508-523
DOI: 10.3390/inorganics2030508


Photophysical Responses in Pt2Pb Clusters Driven by Solvent Interactions and Structural Changes in the PbII Environment
Jesús R. Berenguer, Elena Lalinde, Antonio Martín, M. Teresa Moreno, Santiago Ruiz, Sergio Sánchez, and Hamid R. Shahsavari
Inorg. Chem. 2014, 53, 8770-8785
DOI: 10.1021/ic501458q


Preparation of Pt-Tl Clusters Showing New Geometries. X-ray, NMR and Luminescence Studies
Úrsula Belío, Sara Fuertes and Antonio Martín
Dalton Trans. 2014, 43, 10828-10843
DOI: 10.1039/C4DT00536H


Mononuclear anionic AO2X3 compounds with non-VSEPR structure
María Ángeles García-Monforte, Miguel Baya, María Pilar Betoré, Antonio Martín and Babil Menjón
Dalton Trans. 2014, 43, 7615-7621
DOI: 10.1039/C4DT00525B


Fluorocarbons Modulate the Coordination Sphere of f-Element Complexes
Santiago Álvarez, Babil Menjón
Angew. Chem. Int. Ed. 2014, 53, 2810-2811
DOI: 10.1002/anie.201310916


Synthesis, Characterization, And Computational Study of Complexes Containing Pt...H Hydrogen Bonding Interactions
Miguel Baya, Úrsula Belío and Antonio Martín
Inorg. Chem., 2014, 53, 189-200
DOI: 10.1021/ic402036p


Donor Behaviour of Anionic and Asymmetric Phosphanido Derivatives of Platinum and Palladium
Andersson Arias, Juan Forniés, Consuelo Fortuño, Antonio Martín, Piero Mastrorilli, Vito Gallo, Mario Latronico and Stefano Todisco
Eur. J. Inorg. Chem. 2014, 1679-1693
DOI: 10.1002/ejic.201300808


Addition of Nucleophiles to Phosphanido Derivatives of Pt(III): Formation of P-C, P-N, and P-O Bonds
Andersson Arias, Juan Forniés, Consuelo Fortuño, Susana Ibáñez, Antonio Martín, Piero Mastrorilli, Vito Gallo, and Stefano Todisco
Inorg. Chem. 2013, 52, 11398-11408
DOI: 10.1021/ic401689c


Gold(I) and Gold(III) Trifluoromethyl Derivatives
Sonia Martínez Salvador, Larry Falvello, Antonio Martín and Babil Menjón
Chem. Eur. J. 2013, 19, 14540-14552
DOI: 10.1002/chem.201302142


From a di- and trinuclear phosphanido fragment to tetra- and hexanuclear platinum(II) complexes
Andersson Arias. Juan Forniés, Consuelo Fortuño, and Antonio Martín
Inorg. Chim. Acta 2013, 407, 189-196
DOI: 10.1016/j.ica.2013.07.048


N-Assisted CPh-H Activation in 3,8-Dinitro-6-phenylphenanthridine. New C,N-Cyclometalated Compounds of Platinum(II): Synthesis, Structure, and Luminescence Studies
Violeta Sicilia, Sara Fuertes, Antonio Martín, and Adrián Palacios
Organometallics 2013, 32, 4092-4102
DOI: 10.1021/om400159g


Synthesis and characterisation of a "Pt3Tl" cluster containing an unprecedented trigonal environment for Tl(I)
Úrsula Belío, Sara Fuertes and Antonio Martín
Inorg. Chem. 2013, 52, 5627-5629
DOI: 10.1021/ic400167w


Solvent-induced lone pair activity tuning and vapoluminescence in a Pt2Pb cluster
Jesús R. Berenguer, Elena Lalinde, Antonio Martín, M. Teresa Moreno, Santiago Ruiz, Sergio Sánchez and Hamid R. Shahsavaria
Chem. Commun. 2013, 49, 5067-5069
DOI: 10.1039/C3CC41638K


Oxidatively Induced P-O Bond Formation through Reductive Coupling between Phosphido and Acetylacetonate, 8-Hydroxyquinolinate, and Picolinate Groups
Andersson Arias, Juan Forniés, Consuelo Fortuño, Antonio Martín, Piero Mastrorilli, Stefano Todisco, Mario Latronico, and Vito Gallo
Inorg. Chem. 2013, 52, 5493-5506
DOI: 10.1021/ic4004005


Selective Synthesis of New Half-Lantern Benzoquinolate Platinum Complexes. DFT and Photophysical Studies on the Platinum (II,II) Derivative
Violeta Sicilia, Pilar Borja, José M. Casas, Sara Fuertes and Antonio Martín
J. Organomet. Chem. 2013, 731, 10-17
DOI: 10.1016/j.jorganchem.2013.01.027


Luminescent Pt-Ag Clusters based in Neutral Benzoquinolate Cyclometalated Platinum Complexes
Antonio Martín, Úrsula Belío, Sara Fuertes and Violeta Sicilia
Eur. J. Inorg. Chem. 2013, 2231-2247
DOI: 10.1002/ejic.201201528


Synthesis and Reactivity of the Unsaturated trinuclear Phosphanido Complex [(C6F5)2Pt(μ-PPh2)2Pt(μ-PPh2)2Pt(PPh3)]
Juan Forniés, Consuelo Fortuño, Susana Ibáñez, Antonio Martín, Piero Mastrorilli, Vito Gallo and Athanassios Tsipis
Inorg. Chem. 2013, 52, 1942-1953
DOI: 10.1021/ic3021639


Stepwise Degradation of Trifluoromethyl-Platinum(II) Compounds
Sonia Martínez-Salvador, Juan Forniés, Antonio Martín, Babil Menjón and Isabel Usón
Chem. Eur. J. 2013, 19, 324-337
DOI: 10.1002/chem.201202648


Re-Mediated C-C Coupling of Pyridines and Imidazoles
Maialen Espinal Viguri, Miguel Huertos, Julio Pérez, Lucía Riera and Irene Ara
J. Am. Chem. Soc. 2012, 134, 20326-20329
DOI: 10.1021/ja310981m


Formation of P-C Bond through Reductive Coupling Between Bridging Phosphido and Benzoquinolinate Groups. Isolation of Complexes of the Pt(II)/Pt(IV)/Pt(II) Sequence
Andersson Arias, Juan Forniés, Consuelo Fortuño, Antonio Martín, Mario Latronico, Piero Mastrorilli, Stefano Todisco, Vito Gallo
Inorg. Chem. 2012, 51, 12682-12696
DOI: 10.1021/ic301298p


An Organotransition-Metal Complex with Pentagonal-Pyramidal Structure
María Ángeles García-Monforte, Miguel Baya, Larry Falvello, Antonio Martín, and Babil Menjón
Angew. Chem. Int. Ed. 2012, 51, 8046-8049
DOI: 10.1002/anie.201202819


Heteropolynuclear Pt(II)-M(I) Clusters with a C^N^C Biscyclometalated Ligand
Sara Fuertes, Christopher H. Woodall, Paul R. Raithby, and Violeta Sicilia
Organometallics 2012, 31, 4228-4240
DOI: 10.1021/om300170j


The Trifluoromethyl Group in Transition Metal Chemistry
M. Angeles García-Monforte, Sonia Martínez-Salvador and Babil Menjón
Eur. J. Inorg. Chem. 2012, 4945-4966
DOI: 10.1002/ejic.201200620


New Dicyano Cyclometalated Compounds Containing Pd(II)-Tl(I) Bonds as Building Blocks in 2D Extended Structures: Synthesis, Structure, and Luminescence Studies
Violeta Sicilia, Juan Forniés, Sara Fuertes, and Antonio Martín
Inorg. Chem. 2012, 51, 10581-10589
DOI: 10.1021/ic300808z


Luminescent Benzoquinolate-Isocyanide Platinum(II) Complexes: Effect of Pt...Pt and π...π Interactions on their Photophysical Properties
Juan Forniés, Violeta Sicilia, Pilar Borja, José M. Casas, Alvaro Díez, Elena Lalinde, Carmen Larraz, Antonio Martín, and M. Teresa Moreno
Chem. Asian. J. 2012, 7, 2813-2823
DOI: 10.1002/asia.201200585


A Highly Luminescent Half-Lantern Cyclometalated Platinum (II) Complex: Synthesis, Structure, Luminescence Studies and Reactivity
Violeta Sicilia, Juan Forniés, José M. Casas, Antonio Martín, José A. López, Carmen Larraz , Pilar Borja , Carmen Ovejero, Daniel Tordera and Henk Bolink
Inorg. Chem. 2012, 51, 3427-3435
DOI: DOI 10.1021/ic201910t


Benzoquinolateplatinum(II) Complexes as Building Blocks in the Synthesis of Pt-Ag Extended Structures
Juan Forniés, Susana Ibáñez, Elena Lalinde, Antonio Martín, M. Teresa Moreno and Athanassios C. Tsipis
Dalton Trans. 2012, 41, 3439-3451
DOI: DOI 10.1039/C2DT11885H


Solid-state and solution structure of a hypervalent AX5 compound: Sb(C6F5)5
María Ángeles García-Monforte, Pablo J. Alonso, Irene Ara, Babil Menjón, and Pilar Romero
Angew. Chem. Int. Ed. 2012, 50, 2754-2757
DOI: 10.1002/anie.201108858


Synthesis and Characterization of the Double Salts [Pt(bzq)(CNR)2][Pt(bzq)(CN)2] with Significant Pt...Pt and π...π Interactions. Mechanistic Insights into the Ligand Exchange Process from Joint Experimental and DFT Study
Juan Forniés, Sara Fuertes, Carmen Larraz, Antonio Martín, Violeta Sicilia and Athanassios C. Tsipis
Organometallics 2012, 31, 2729-2740
DOI: DOI 10.1021/om201036z


A square-pyramidal organochromium(V) compound
M. Ángeles García-Monforte, Pablo J. Alonso, Ana B. Arauzo, Antonio Martín, Babil Menjón and Conrado Rillo
Dalton Trans. 2012, 41, 1297-1303
DOI: 10.1039/C1DT11376C


Behavior of Neutral Phospido Derivatives of Platinum and Palladium toward Silver Centers
Juan Forniés, Consuelo Fortuño, Susana Ibáñez and Antonio Martín
Inorg. Chem. 2011, 50, 10798-10809
DOI: 10.1021/ic201354s


Efficient and stereoselective syntheses of isomeric trifluoromethyl-platinum(IV) chlorides
Sonia Martínez Salvador, Pablo J. Alonso, Juan Forniés, Antonio Martín and Babil Menjón
Dalton Trans. 2011, 40, 10440-10447
DOI: 10.1039/C1DT10557D


Highly Trifluoromethylated Platinum Compounds
Sonia Martínez Salvador, Juan Forniés, Antonio Martín and Babil Menjón
Chem. Eur. J. 2011, 17, 8085-8097
DOI: 10.1002/chem.201100626


A Gold Carbonyl Compund Stabilized by a Trifluoromethyl Group
Sonia Martínez Salvador, Juan Forniés, Antonio Martín and Babil Menjón
Angew. Chem. Int. Ed. 2011, 50, 6571-6574
DOI: 10.1002/anie.201101231


Pt-Ag clusters and their neutral mononuclear Pt(II) starting complexes: structural and luminescence studies
Juan Forniés, Violeta Sicilia, José M. Casas, Antonio Martín, José A. López, Carmen Larraz, Pilar Borja and Carmen Ovejero
Dalton Trans. 2011, 40, 2898-2912
DOI: 10.1039/C0DT01451F


Synthesis, Dynamic Behavior, and Reactivity of New Unsaturated Heterotrinuclear 46 Valence Electron Complexes
Juan Forniés, Consuelo Fortuño, Susana Ibañez, Antonio Martín, and Pilar Romero
Inorg. Chem. 2011, 50, 285-298
DOI: 10.1021/ic101934t


Synthesis, characterisation and magnetic properties of octahedral chromium(III) compounds with six C-donor ligands
Pablo J. Alonso, Ana B. Arauzo, M. Angeles García-Monforte, Inés García-Rubio, Antonio Martín, Babil Menjón and Conrado Rillo
Dalton Trans. 2011, 40, 853-861
DOI: 10.1039/c0dt00891e


Structural and Luminescence Studies on π...π and Pt...Pt Interactions in Mixed Chloro-Isocyanide Cyclometalated Platinum(II) Complexes
Álvaro Díez, Juan Forniés, Carmen Larraz, Eleana Lalinde, José A. López, Antonio Martín, M. Teresa Moreno, and Violeta Sicilia
Inorg. Chem. 2010, 49, 3239-3251
DOI: 10.1021/ic902094c


Synthesis and characterization of neutral and anionic carbonyl derivatives of palladium(II)
Irene Ara, Juan Forniés, Antonio Martín, L. Francisco Martín, Babil Menjón and Helvia Miedes
Dalton Trans. 2010, 39, 7301-7309
DOI: 10.1039/c0dt00014k


Organoniobium compounds with [NbR4] and NbR4 stoichiometries
Pablo J. Alonso, Irene Ara, Ana B. Arauzo, María Ángeles García-Monforte, Babil Menjón, and Conrado Rillo
Angew. Chem. Int. Ed. 2010, 49, 6143-6146
DOI: 10.1002/anie.201002666


Trapping a Difluorocarbene-Platinum Fragment by Base Coordination
Sonia Martínez-Salvador, Babil Menjón, Juan Forniés, Antonio Martín, Isabel Usón
Angew. Chem. Int. Ed. 2010, 49, 4286-4289
DOI: 10.1002/anie.2000907031


One-Pot and Step-by-Step N-Assisted CPh−H Activation in 2-(4-Bromophenyl)imidazol[1,2-a]pyridine: Synthesis of a New C,N-Cyclometalated Compound [{Pt(C^N)(μ-Cl)}2] as Precursor of Luminescent Platinum(II) Compounds
Juan Forniés, Violeta Sicilia, Carmen Larraz, José A. Camerano, Antonio Martín, José M. Casas, and Athanassios C. Tsipis
Organometallics 2010, 29, 1396-1405
DOI: 10.1021/om901032v


A new class of polymeric complexes having Pt–Ag interactions: Crystal structure of |{[(PPh3)(C6F5)Pt(μ-Cl)]2Ag}(μ-Cl)2Ag(MeOH)|n
Irene Ara, Javier Aranaz and Juan Forniés
J. Fluorine Chem. 2010, 131, 1103-1107
DOI: 10.1016/j.jfluchem.2010.04.008


Homoleptic Organoderivatives of High-Valent Nickel(III)
Pablo J. Alonso, Ana B. Arauzo, María Angeles García-Monforte, Antonio Martín, Babil Menjón
Chem. Eur. J. 2009, 15, 11020-11030
DOI: 10.1002/chem.200901259


Insertion of CO and Strained Olefins into Organometallic (Ferrocenylmethyl)phosphane Palladium Complexes
Maria Michela Dell'Anna, Daniela Giardina-Papa, Susana Ibáñez, Antonio Martín, Piero Mastrorilli, Cosimo Francesco Nobile, Maurizio Peruzzini
Eur. J. Inorg. Chem. 2009, 4454-4463
DOI: 10.1002/ejic.200900527


Behavior of P-Pt and P-Pd Bonds in Phosphido Complexes toward Electrophilic Fragments
Ester Alonso, Juan Forniés, Consuelo Fortuño, Agustí Lledós, Antonio Martín, and Ainara Nova
Inorg. Chem. 2009, 48, 7679-7690
DOI: 10.1021/ic900415m


Self-Assembly of Luminescent Alkynyl-Based Platinum-Cadmium Complexes Containing Auxiliary Diimine or Terpyridine Ligands
Jesús R. Berenguer, Belén Gil, Julio Fernández, Juan Forniés, and Elena Lalinde
Inorg. Chem. 2009, 48, 5250-5262
DOI: 10.1021/ic9002109


Oxidative Addition of Halogens to Homoleptic Perfluoromethyl or Perfluorophenyl Derivatives of Platinum(II): A Comparative Study
Babil Menjón, Sonia Martínez-Salvador, Miguel A. Gómez-Saso, Juan Forniés, Larry R. Falvello, Antonio Martín, Athanassios Tsipis
Chem. Eur. J. 2009, 15, 6371-6382
DOI: 10.1002/chem.200900323


Synthesis and Luminescence of Cyclometalated Compounds with Nitrile and Isocyanide Ligands
Álvaro Díez, Juan Forniés, Sara Fuertes, Elena Lalinde, Carmen Larraz, José A. López, Antonio Martín, M. Teresa Moreno, and Violeta Sicilia
Organometallics 2009, 28, 1705-1718
DOI: 10.1021/om800845c


Extended structures containing Pt(II)-Tl(I) bonds. Effect of these interactions on the luminescence of cyclometalated Pt(II) compounds
Juan Forniés, Sara Fuertes, Antonio Martín, Violeta Sicilia, Belén Gil and Elena Lalinde
Dalton Trans. 2009, 2224-2234
DOI: 10.1039/b819323a


Unsymmetrical Platinum(II) Phosphido Derivatives: Oxidation and Reductive Coupling Processes Involving Platinum(III) Complexes as Intermediates
Irene Ara, Juan Forniés, Consuelo Fortuño, Susana Ibáñez, Antonio Martín, Piero Mastrorilli and Vito Gallo
Inorg. Chem. 2008, 47, 9069-9080
DOI: 10.1021/ic8011124


Synthesis of Binuclear Platinum Complexes Containing the Ligands 8-Naphthyridine, 2-Aminopyridine, and 7-Azaindolate. An Experimental Study of the Steric Hindrance of the Bulky Pentafluorophenyl Ligands in the Synthesis of Binuclear Complexes
José M. Casas, Beatriz E. Diosdado, Juan Forniés, Antonio Martín, Ángel Rueda and A. Guy Orpen
Inorg. Chem. 2008, 47, 8767-8775
DOI: 10.1021/ic8006475


[Pt]2Pb trimetallic systems: impact of the anionic platinum fragment on the lead environment and photoluminescence
J. R. Berenguer, A. Díez, J. Fernández, J. Forniés, A. García, B. Gil, Elena Lalinde and M. T. Moreno
Inorg. Chem. 2008, 47, 7703-7716
DOI: 10.1021/ic8006876


New Water Soluble and Luminescent Platinum(II) Compounds, Vapochromic Behavior of [K(H2O)][Pt(bzq)(CN)2], New Examples of the Influence of the Counterion on the Photophysical Properties of d8 Square-Planar Complexes
Juan Forniés, Sara Fuertes, J. Antonio López, Antonio Martín, and Violeta Sicilia
Inorg. Chem. 2008, 47, 7166-7176
DOI: 10.1021/ic800265q


Halide Addition/Abstraction in Phosphido Derivatives: Isolation of the Thallium and Silver Intermediates
Juan Forniés, Consuelo Fortuño, Susana Ibáñez, and Antonio Martín
Inorg. Chem. 2008, 47, 5978-5987
DOI: 10.1021/ic800294c


Luminescent One- and Two-dimensional Extended Structures and a Loosely Associated Dimer Based on Platinum(II)-Thallium(I) Backbones
Juan Forniés, Ana García, Elena Lalinde, and M. Teresa Moreno
Inorg. Chem. 2008, 47, 3651-3660
DOI: 10.1021/ic702180c


One-dimensional phosphinite platinum chains based on hydrogen bonding interactions and phosphinite tetranuclear platinum(II)-thallium(I) complexes
Alvaro Díez, Juan Forniés, Julio Gómez, Elena Lalinde, Antonio Martín, M. Teresa Moreno and Sergio Sánchez
Dalton Trans. 2007, 3653-3660
DOI: 10.1039/b704852a


New advances in homoleptic organotransition-metal compounds: The case of perhaloaryl ligands
M. Angeles García-Monforte, P. J. Alonso, Juan Forniés, and Babil Menjón
Dalton Trans. 2007, 3347-3359
DOI: 10.1039/B708938D


Synthesis and characterization of new paramagnetic tetraaryl derivatives of chromium and molybdenum
Pablo J. Alonso, Juan Forniés, María Ángeles García-Monforte, Antonio Martín, Babil Menjón and Conrado Rillo
J. Organomet. Chem. 2007, 692, 3236-3247
DOI: 10.1016/j.jorganchem.2007.03.028


New Mono- and Polynuclear Alkynyl Complexes Containing Phenylacetylide as Terminal or Bridging Ligand. X-ray Structures of the Compounds NBu4[Pt(CH2C6H4P(o-tolyl)2C,P)(CCPh)2], [Pt(CH2C6H4P(o-tolyl)2C,P)(CCPh)(CO)], [{Pt(CH2C6H4P(o-tolyl)2C,P)(μ-CCPh)}2], and [{Pt(CH2C6H4P(o-tolyl)2C,P)(CCPh)2Cu}2]
José M. Casas, Juan Forniés, Sara Fuertes, Antonio Martín, and Violeta Sicilia
Organometallics 2007, 26, 1674-1685
DOI: 10.1021/om061102m


An organometallic tetranuclear cluster with phosphine and phosphido ligands in nonclassical bonding modes: X-ray structural characterization
Naima Chaouche, Juan Forniés, Consuelo Fortuño, Abdelaziz Kribii and Antonio Martín
J. Organomet. Chem. 2007, 692, 1168-1172
DOI: 10.1016/j.jorganchem.2006.11.018