Multinuclear (³¹P, ¹⁹⁵Pt, ¹⁹F) solid-state NMR experiments on (nBu₄N)₂[(C₆F₅)₂Pt(μ-PPh₂)₂Pt(C₆F₅)₂] (1), [(C₆F₅)₂Pt(μ-PPh₂)₂Pt(C₆F₅)₂](Pt-Pt) (2), and cis-Pt(C₆F₅)₂(PHPh₂)₂ (3) were carried out under cross-polarization/magic-angle-spinning conditions or with the cross-polarization/Carr-Purcell Meiboom-Gill pulse sequence. Analysis of the principal components of the ³¹P and ¹⁹⁵Pt chemical shift (CS) tensors of 1 and 2 reveals that the variations observed comparing the isotropic chemical shifts of 1 and 2, commonly referred to as "ring effect", are mainly due to changes in the principal components oriented along the direction perpendicular to the Pt₂P₂ plane. DFT calculations of ³¹P and ¹⁹⁵Pt CS tensors confirmed the tensor orientation proposed from experimental data and symmetry arguments and revealed that the different values of the isotropic shieldings stem from differences in the paramagnetic and spin-orbit contributions.