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A Multifunctional Dysprosium-Carboxylato 2D Metall–Organic Framework
Jonay González, Pablo Sevilla, Guillem Gabarró-Riera, Jesús Jover, Jorge Echeverría, Sara Fuertes, Ana Arauzo, Elena Bartolomé, E. Carolina Sañudo
Angew. Chem. 2021, 60, 12001-12006
DOI: 10.1002/anie.202100507
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We report the microwave assisted synthesis of a bidimensional (2D) MOF of formula [Dy(MeCOO)(PhCOO)2]n (1) and its magnetically diluted analogue [La0.9Dy0.1(MeCOO)(PhCOO)2] (1 d). 1 is a 2D material with single-ion-magnet (SIM) behaviour and 1 d is a multifunctional, magnetic and luminescent 2D material. 1 can be exfoliated into stable nanosheets by sonication.
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